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Reagents for Alkylation & Esterification

Alkylation is the replacement of the active hydrogen in R-COOH, R-OH, R-SH, R-NH, R-NH2, R-CONH2, R-CONH-R' with an alkyl group, or sometimes an aryl group. Esterification is the first choice for derivatization of carboxylic acids and other acidic functional groups. Acids are reactive compounds, and are too polar to be well separated by gas chromatography; underivatized acids tend to tail because of adsorption and non-specific interactions with the column.

 
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Product #
Description
362832 (Trimethylsilyl)diazomethane solution 2.0 M in hexanes
52517 1,1,1,3,3,3-Hexafluoro-2-propanol puriss. p.a., for GC, ≥99.8% (GC)
33053 2,2-Dimethoxypropane bottle of 25 g
17910 2,3,4,5,6-Pentafluorobenzyl bromide puriss., ≥99.0% (GC)
17403 2,3-Dihydroxy-biphenyl purum, ≥98.0% (HPLC)
D141208 2-Chloro-N,N-dimethylethylamine hydrochloride 99%
24362 2-Chloro-N,N-dimethylethylamine hydrochloride purum, ≥98.0% (AT)
05576 Boron trifluoride-ethanol puriss., ~10% (~1.3 M) in ethanol
15716 Boron trifluoride-methanol solution puriss., ~10% (~1.3�M), for esterification of fatty acids for GC purposes
83253 Bortrifluoride - 1-butanol solution puriss., for esterification of fatty acids for GC purposes
69534 Derivatizing agents, Set for GC: Alcohols with boron trifluoride
72558 Derivatizing agents, Set for GC: Alcohols with hydrogen chloride
D28000 Diazald® 99%
35009 Hydrogen chloride – 2-propanol solution according to DIN 51558-1, 0.1 M
17933 Hydrogen chloride – 2-propanol solution puriss. p.a., for GC, ~1.25 M (T)
17934 Hydrogen chloride – ethanol solution puriss. p.a., for GC, ~1.25 M (T)
17935 Hydrogen chloride – methanol solution puriss. p.a., for GC, ~1.25 M (T)
395005 N,N-Dimethylformamide di-tert-butyl acetal derivatization grade
394971 N,N-Dimethylformamide diethyl acetal derivatization grade
394963 N,N-Dimethylformamide dimethyl acetal derivatization grade
394998 N,N-Dimethylformamide dipropyl acetal derivatization grade
76735 O-(2,3,4,5,6-Pentafluorobenzyl)hydroxylamine hydrochloride puriss. p.a., derivatization grade (for GC), ≥99.0% (AT)
77265 Pentafluoroiodoethane purum, ≥97.0% (GC)
79266 Trimethylphenylammonium hydroxide solution puriss. p.a., for GC, ~0.5 M in methanol
92732 Trimethylsulfonium hydroxide solution purum, derivatization reagent for GC, ~0.25 M in methanol